Stability of s-, p-, and d-element diphosphates in water

2007

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DOI 10.1134/s0036023607090082
Data confidence 70 medium
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Abstract

The mean atomic Gibbs energies of formation of (Δ f Ḡ at 0 ) of s-, p-, and d-element diphosphates have been calculated using ion increments of the Gibbs energy (Δ f G 0). The diphosphate hydrolysis kinetics is considered, and a correlation between the Δ f Ḡ at 0 values and the hydrolysis rate constants is presented.