Аннотация
The mean atomic Gibbs energies of formation of (Δ f Ḡ at 0 ) of s-, p-, and d-element diphosphates have been calculated using ion increments of the Gibbs energy (Δ f G 0). The diphosphate hydrolysis kinetics is considered, and a correlation between the Δ f Ḡ at 0 values and the hydrolysis rate constants is presented.