Unexpectedly Easy Noncatalytic Allyl Group Transfer from Allyl Sulfides to Secondary Phosphine Sulfides

N. A. Chernysheva, S. I. Verkhoturova, Arailym M. Nalibayeva, Gaukhar K. Bishimbayeva, S. N. Arbuzova, Sergey V. Zinchenko, Boris Aleksandrovich Trofimov

2023

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DOI 10.1134/s107042802303003x

Data confidence 70 medium

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Abstract

Abstract The allylation of secondary phosphine sulfides with allyl sulfides under mild catalyst-free and solvent-free conditions at 80°C unexpectedly afforded allyl(diorganyl)phosphine sulfides in up to 79% yield. The products are capable of adding the initial secondary phosphine sulfides at the allyl group during the process to give the corresponding anti-Markovnikov adducts, propane-1,3-diylbis(diorganylphosphine sulfides), that are promising as extractants for heavy metals and ligands for metal-complex catalysts.