DEVELOPMENT AND INVESTIGATION OF PROPERTIES OF MIXED CATALYSTS FOR VAPOR-PHASE HYDRATION OF ACETYLENE

2022

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DOI 10.52013/2658-7556-73-11-44
Data confidence 70 medium
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Abstract

In order to develop new catalysts for the synthesis of acetaldehyde by vapor-phase hydration of acetylene, new mono- and bifunctional catalysts based on cadmium, zinc, chromium, and iron compounds on supports were developed and their most important textural characteristics were studied. It was shown that zinc oxide and cadmium fluoride are bifunctional catalysts, in the presence of which acetaldehyde was synthesized with a yield of 69.0 — 70.0%. It has been established that the stability of their operation before regeneration exceeds more than 100 hours, i.e. 1.3 times more than industrial cadmium-calcium phosphate catalyst.