Development of an Oxidizing-Distillation Technology for the Extraction of Tellurium from a Tellurium-Containing Middling

2022

Closed access Metadata (CSL-JSON)
DOI 10.11159/mmme22.128
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

In this paper, the results of studying aimed at tellurium extraction from its compound with copper in the form of oxides by the pyrometallurgical method are presented.Technical copper telluride of Kazakhmys Corporation LLP containing crystalline phases, %: Cu 7 Te 4 -36.5;Cu 5 Te 3 -28.5;Cu 2 Te -12.9;Cu 2.5 SO 4 (OH) 3 •2H 2 O -16.2 and Cu 3 (SO 4 )(OH) 4 -6.0 was used as an object of research.As a result of the physical and chemical research and technological experiments, the fundamental possibility of processing technical copper telluride by oxidative distillation roasting with the extraction of tellurium into a separate product has been shown.Air oxygen was used as an oxidant.It has been established that a pressure decrease at the same temperature entails an increase in the degree of tellurium extraction.However, from a technological point of view, the value of the degree of tellurium extraction (93.0-98.0%) at all pressures (within 1 hour) is achieved at a temperature of 1100 °C.Increasing the exposure to 3 hours has a minor beneficial effect.The derived condensate is a free-flowing mixture of crystalline phases of tellurium dioxide and tellurium oxysulfate.This condensate is a middling product for further production of elemental tellurium.