ON INTERDEPENDENCY OF ELECTROCHEMICAL AND PHYSICOCHEMICAL METRICS OF D-METALS COMPLEXES WITH SULFUR-CONTAINING LIGANDS

2015

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DOI 10.17073/0021-3438-2014-3-10-15
Data confidence 70 medium
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Abstract

There were calculated redox potentials of metal complexes, refraction values and polarizability factors of the donor – organic ligands. There were specified correlation dependences between transition constants of outer-sphere complexes into innerspheres ones and redox potentials of complexes, taking into account structural and energetic features ligands and metals ions.