Developing functional epoxy/graphene composites using facile in‐situ mechanochemical approach

Qingshi Meng, Yuanyuan Feng, Sensen Han, Fei Yang, Murat Demiral, Fanze Meng, Sherif Araby

2023

Closed access Metadata (CSL-JSON)
DOI 10.1002/app.53681
Data confidence 85 high
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

Abstract The awareness of developing eco‐friendly polymer composites via green chemistry attract much attention in the recent years. In the current work, we explore preparing functional epoxy/ graphene nanocomposites using mechanochemical approach. Graphene platelets (GnPs) were modified with long‐chain surfactant via high‐energy ball milling. Modified‐GnPs (m‐GnPs) promote the dispersion quality and interface strength with epoxy matrix leading to higher mechanical properties, and better electrical and thermal conductivity compared to unmodified GnPs system. At 2.0 vol% m‐GnPs, elastic modulus, tensile strength, and thermal conductivity of epoxy were improved by 889%, 163%, and 105%, respectively. In addition, percolation threshold of electrical conductivity was observed at 0.71 vol% m‐GnPs. Halpin‐Tsai micromechanical model was able to predict the elastic modulus of the epoxy/GnP nanocomposites. The model results were compared experimental measurements. Furthermore, the measurements showed epoxy/m‐GnP film possess high sensitivity to mechanical strains and impact loads. The current work gives a step forward to use mechanochemistry approach in the production of functional epoxy/graphene composites.