About Some Properties and Features of Differential and Integrated Representations in the Theory of Thermodynamic Functions

2016

Full text Open access: Gold Metadata (CSL-JSON)
DOI 10.17516/1999-494x-2016-9-8-1314-1325
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

In article the comparative analysis of differential and integrated consideration of thermodynamic process is carried out.It is shown that use of the rule of replacement of variables of integration leads to correct output of main thermodynamic functions (an enthalpy, Helmholtz's function and Gibbs's function).It occurs through integrated consideration of thermodynamic process when parameters change in final (limited) intervals.It is established that Integrated consideration of the law of energy conservation in general view for the moving final volume of liquid or gas leads to «expanded» option of formula for the first law of thermodynamics.At the same time the equations recorded in differential form taking into account different types of technical work.Communications between the work of pushing through of some volume of gas and work connected with pressure at expansion of gas volume are shown.