Equilibrium kinetic analysis of a model mixture of anthracene and benzothiophene

М. И. Байкенов, A.B. Tateeva, Zh. S. Akhmetkarimova, Almas Tusipkhan, А. Ж. Матаева, К. К. Есенбаева

2015

Closed access Metadata (CSL-JSON)
DOI 10.3103/s0361521915050031
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

The kinetic and thermodynamic parameters of the hydrogenation of an anthracene–benzothiophene model mixture were calculated. The rate constants of forward and reverse reactions, the equilibrium constant, the activation energies, and the heat effects of hydrogenation reactions were determined by equilibrium kinetic analysis for second-order reactions in a model mixture of anthracene and benzothiophene in the presence of an iron-containing catalyst over a temperature range of 648–698 K at a pressure of 6 MPa.