The kinetics of oxidative alcoholysis of zinc phosphide in the presence of oxygen and the FeCl3-I2 mixed catalyst in solution in butanol

2009

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DOI 10.1134/s0036024409050094
Data confidence 70 medium
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Abstract

The oxidative alkoxylation of zinc phosphide to tributyl phosphate occurred at a high rate and with high selectivity in a solution of FeCl 3 -I 2 in butanol at 50–70°C. The kinetic characteristics and optimum conditions of the process were determined. The experimental and literature data were used to identify key stages of the formation of tributyl phosphate in the presence of the mixed catalytic system.