Stereocontrolled eliminacion-cyclization of (+)-hanphylline

2012

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DOI 10.15328/chemb_2012_1302-305
Data confidence 70 medium
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Abstract

The reactions of stereocontrolled 1,5-cyclization of E, E-hermacrane hanphylline are studied. Cis-guaianolides is as a result synthesized. The mechanism of 1,5- carbocyclization is considered and the chart of biogenetic intercommunication of guaianolides is offered in Achillea nobilis L.