Synthesis and steric structure of aryloxypropynyl alcohols of the phosphinane series

2006

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DOI 10.1134/s1070363206030157
Data confidence 70 medium
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Abstract

Phenoxy-and benzyloxypropynyl alcohols of the phosphinane series are synthesized. The steric structure of individual isomers is established by means of 1 H and 13 C NMR spectroscopy. Stereodirection of the ethynylation of trans- and cis -2,5-dimethyl-1-phenyl-2-thioxo-λ 5 -phosphinane-4-ones is studied.