Three-Cation Scandium Borates RxLa1−XSc3(BO3)4(R = Sm, Tb): Synthesis, Structure, Crystal Growth and Luminescent Properties

Aleksander E. Kokh, Artem B. Kuznetsov, К. А. Кох, Nadezda G. Kononova, Vyacheslav S. Shevchenko, Bolat Uralbekov, Asset Bolatov, В. А. Светличный

2019

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DOI 10.1007/978-3-030-22974-0_64

Data confidence 85 high

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Abstract

Complex ortohoborates of rare earth metals with the general chemical formula R x La 1−x Sc 3 (BO 3 ) 4 (R = Sm, Tb) have been obtained by solid state synthesis and spontaneous crystallization. These crystals belong to the huntite family with the space group R32 and for x = 0.5 have unit cell parameters a = 9.823(6), c = 7.975(3) (SLSB) and a = 9.803(3), c = 7.960(4) Å (TLSB).