Conformation of the α-Methylene-γ-lactone Ring and Violation of Geissman's Rule in Sesquiterpene Lactones

1995

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DOI 10.1070/mc1995v005n02abeh000449
Data confidence 85 high
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Abstract

The dependence of the CC–CO group chirality on the conformation of the α-methylene-γ-lactone ring in sesquiterpene lactones has been established; the known cases in which Geissman's rule is violated are explained by inversion of this ring.