Electric smelting of phosphorites with production of a ferroalloy, calcium carbide and sublimation of phosphorus

2023

Full text Open access: Hybrid Metadata (CSL-JSON)
DOI 10.51301/ejsu.2023.i6.02
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

The article presents the results of a study of the interaction of phosphorites from the Chulaktau deposit of the Karatau basin with coke and steel shavings. The studies were carried out by computer thermodynamic modeling using the HSC-10 software package, together with mathematical planning of experiments, as well as by electric phosphorite melting in an electric arc furnace. On the basis of the conducted studies it was established that the joint formation of intermediate products from the systems Ca3(PO4)2-SiO2-C-Fe is possible at the temperature ˃ 1635-1702ºC. Based on the obtained volumetric and planar images of the coke and steel shavings effect on the technological parameters of the phosphorite’s electric smelting, it was found that in order to produce FS25 grade ferrosilicon containing 20-30% of Si and calcium carbide with a capacity of 245.1-248.1 dm3/kg (2nd grade), the process should be carried out in the presence of 52-58% of coke and 24.4-38% of steel shavings. In this case, the extraction degree of silicon into the ferroalloy was 70-80%, and calcium into calcium carbide – 60-70%.