Preparation of silver chloride nanoparticles by a mechanical treatment of the system NH4Cl−AgNO3−NH4NO3

Farit Kh. Urakaev, Mukhambetkali M. Burkitbayev, Batukhan Tatykayev, Bolat Uralbekov

2014

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DOI 10.15328/chemb_2014_253-59

Data confidence 70 medium

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Abstract

Silver chloride nanoparticles dispersed within ammonium nitrate matrix have been prepared though displacement mechanochemical reaction NH4Cl + AgNO3 + z NH4NO3 = (z+1) NH4 NO3 + AgCl at various z coefficients z1 = 7.22 and z2 = 3.64. The intermediate compound of NH4Ag(NO3)2 were recorded after mechanochemical processing of studied system. By using simultaneous TG and DSC measurements possibilities to prepare silver chloride in its free form have been discussed by using thermal treatment.