Stability of 3d-element cyclotetraphosphates in water

2007

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DOI 10.1134/s0036023607090094
Data confidence 70 medium
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Abstract

The hydrolysis kinetics of the anion in 3d-element cyclotetraphosphates is considered. The thermodynamic functions of formation (Δ f H 0, Δ f G 0, and Δ f Ḡ at 0 ) of the cyclotetraphosphates are calculated using the ion increment method. A linear correlation is established between and log K Δ f Ḡ at 0 for these compounds.