Phase Diagrams of Fullerenol-d–LaCl3–H2O and Fullerenol-d–GdCl3–H2O Systems at 25°С

В. А. Кескинов, Konstantin N. Semenov, Т. С. Гольцов, Nikolay A. Charykov, Nikita E. Podolsky, A. V. Kurilenko, Zh. K. Shaimardanov, Botagoz K. Shaimardanova, N. A. Kulenova

2019

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DOI 10.1134/s0036024419120124

Data confidence 70 medium

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Abstract

Abstract Isothermal phase diagrams of ternary systems fullerenol-d–LaCl3–H2O and fullerenol-d–GdCl3–H2O at 25°C are studied via saturation technique. Solubility diagrams are found to be of a simple eutonic type and are characterized by the salting-out of chloride upon adding fullerenol-d, and short branches of LaCl3 · 7H2O and GdCl3 · 6H2O crystallization, where the salting-in effect is observed.