Abstract
Heat pumps are widely recognized as energy-efficient technologies for domestic hot water production. However, conventional single-stage vapor compression heat pumps utilizing ambient air as the heat source are limited in delivering outlet water temperatures above 323 K under low ambient conditions. This limitation restricts their applicability in continental climates characterized by large diurnal and seasonal temperature variations. Two-stage cascade systems can achieve higher outlet temperatures exceeding 343 K, but they require two compressors, resulting in increased energy consumption and higher capital costs. To overcome these drawbacks, the present study proposes an auto-cascade compression heat pump system employing an environmentally friendly binary zeotropic refrigerant mixture to achieve water outlet temperatures above 343 K with improved efficiency and reduced system complexity. In addition, solar collectors are integrated to enhance low-grade heat extraction from the environment. A numerical simulation of the proposed auto-cascade system was conducted for binary zeotropic refrigerant mixtures including R32/R134a, R32/R1234yf, R32/R1234ze, and R32/R245fa within an ambient temperature range of 223–273 K. The results show that the coefficients of performance (COP) for R32/R134a, R32/R1234yf, and R32/R1234ze mixtures vary between 2.72 and 2.75, while that of R32/R600a reaches 2.55. Based on the comparative analysis, the R32/R134a mixture demonstrated the best performance and is recommended as a promising working fluid for auto-cascade heat pump systems designed for water heating applications in continental climate regions. Keywords: Auto-cascade Heat Pump, Zeotropic Mixture, Continental Climate, Water Heating, COP