Radiation-stimulated adsorption processes on the surface of beryllium oxide

Chimica Techno Acta, 2022

Full text Open access: Gold Metadata (CSL-JSON)
DOI 10.15826/chimtech.2022.9.1.06
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

The paper presents the study results of photo and gamma radiation effect on the beryllium oxide (BeO) surface properties. Photoadsorption studies of О2 on BeO by the methods of infrared (IR) spectroscopy and manometry with a change in the temperature of preliminary annealing from 473 to 1073 K show that samples subjected to preliminary training at 473 K are most active. The maximum of adsorption activity on g-irradiated beryllium oxide is observed on the samples annealed at 673 K before the irradiation. The maximum of paramagnetic centers (PMCs) is also observed on samples annealed at this temperature. Comparison of electron paramagnetic resonance (EPR) and adsorption studies shows that absorption of H2 and O2 leads to the destruction of paramagnetic centers. It is assumed that, upon irradiation, adsorption centers with electron and hole modes are formed on the surface of BeO.