Joint synthesis of acetone and acetaldehyde from acetylene

2020

Closed access Metadata (CSL-JSON)
DOI 10.5958/2278-4853.2020.00246.3
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

The study investigated the possibility of using catalysts based on compounds of cadmium, zinc and other elements filled with d10 orbital electrons with a number of polyfunctional properties, as well as promoted by compounds of various metals in the hydration reaction of acetylene and its derivatives. The hydration reaction of acetylene produces acetaldehyde or acetone, depending on the composition and nature of the catalyst used under the same conditions. In particular, the formation of acetylene at 360-440°C in the presence of cadmium fluoride catalyst containing 20 % CdF2, 5,0 % AlF3, 75 % Al2O3 formation of acetaldehyde when reacting with water = 1: 3 - 1: 5, cadmium fluoride, it was found that when catalysts containing zinc, iron, nickel, cobalt compounds are used instead of aluminum fluoride, the process leads to the formation of acetone.