Reactions of derivatives of phosphorylacetic acid hydrazides with 3,5-di-tert-butyl-4-hydroxybenzyl acetate

2019

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DOI 10.1080/00397911.2019.1681453
Data confidence 85 high
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Abstract

To obtain new polyfunctional inhibitors of radical-chain oxidative processes, C- and N-benzylation of a number of phosphorylacetic acid hydrazide derivatives is realized in their reactions with 3,5-di-tert-butyl-4-hydroxybenzyl acetate. N-benzylation of mixtures of Z and E isomers of hydrazones of phosphorylacetic acid derivatives proceeds stereoselectively with the formation of only EC=N isomers.