Thermodynamic analysis of obtaining ferroalloy from silicon-aluminum-containing silica clay

2017

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DOI 10.23939/chcht11.04.410
Data confidence 70 medium
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Abstract

The article presents results of thermodynamic modeling of Fe-Si-Al complex containing alloy of the silica clay (77.8 % Al 2 O 3 , 11.6 % Al 2 O 3 ).The modeling is based on the principle of minimum Gibbs energy and fulfilled by means of software complex HSC-5.1.It was found that the joint reduction of silicon and aluminum from an amorphous SiO 2 and Al 2 O 3 is characterized by higher thermodynamic probability than from a mixture of a crystalline SiO 2 and Al 2 O 3 .At the silicon reduction there is the undesirable formation of a gaseous SiO; the transition degree of silicon in SiO can be reduced by means of decrease in temperature and increase in carbon content.