Modeling of systems with aqueous solutions of UO2+2 salts. Asymmetric model of excess thermodynamic functions, based on virial expansion of the Gibbs free energy of the solution, VD-AS

Nikolay A. Charykov, Konstantin N. Semenov, A. V. Kurilenko, В. А. Кескинов, D. G. Letenko, N. A. Kulenova, Andrey A. Zolotarev, Клепиков Вячеслав Васильевич

2017

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DOI 10.1134/s1066362217020059
Data confidence 70 medium
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Abstract

An asymmetric model of virial expansion of the Gibbs free energy of solution, VD-AS, was suggested. Partial and molar thermodynamic functions of UO 2 (ClO 4 ) 2 –H 2 O, UO 2 Cl 2 –H 2 O, and UO 2 (NO 3 ) 2 –H 2 O binary solutions at 25°C were calculated using this model. The calculations show that the solutions are characterized by different, sometimes extremely large, deviations from ideality. The suggested model is considerably more accurate and stable than the most widely used Pitzer’s model of electrolyte solutions.