Ionization constants of boronic acids and their complexation with diols

2010

Closed access Metadata (CSL-JSON)
DOI 10.1134/s003602441003012x
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

Ionization constants of a number of boronic acids were determined spectrophotometrically in aqueous solutions. The effect of different substituents on their acid properties is considered. The strongest acids are shown to be phenylboronic acid derivatives containing a nitro group. A model study of the interaction between boronic acids and polyvinyl alcohol depending on pH is analyzed to reveal the optimum conditions for the formation of a stable boronate-diol complex.