CHLORINE FREE SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS BASED ON THE FUNCTIONALIZATION OF WHITE PHOSPHORUS (P4)

Rumia R. Abdreimova, Dina N. Akbayeva, Gulshara S. Polimbetova, Anne‐Marie Caminade, Jean-Pierre Majorals

2000

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DOI 10.1080/10426500008045007
Data confidence 70 medium
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Abstract

Oxidative alkoxylations of P4 in toluene-alcohol solutions are studied. These reactions need oxygen, a catalyst (PdCl2, RuOHCl3, RuCl3) and a co-oxidant (CuCl2, NaNO2, FeCl3, 1,4-henzoquinone, NaBrO3). Trialkylphosphates (RO)3P(O) and dialkylphosphites (RO)2P(O)H are the major products of the reaction. Kinetic experiments concerning the rate of absorption of O2 during these reactions are also reported.