Non-variant phenomena in heterogeneous systems. New type of solubility diagrams points

2023

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DOI 10.29328/journal.aac.1001047
Data confidence 70 medium
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Abstract

The article gives a general classifi cation of non-invariant points in phase equilibrium diagrams of all possible types. The complete topological isomorphism of the diagrams of fusibility, solubility, and liquid-vapor equilibria in various sets of variables is demonstrated. The stability of monovariant equilibria near the non-variant points is investigated. Recurrent formulas for calculating the number of topological elements of phase diagrams are given. A previously undescribed type of non-invariant points and phase processes in the solubility diagrams is described and characterized. The last ones have no topological analogs in other types of diagrams. Thus, we have carried out, as far as is available to the authors, a complete classifi cation of invariant points and invariant processes in phase equilibrium diagrams of an arbitrary type and with an arbitrary number of components.