Study of Gas Swelling Processes under Irradiation with Protons and He2+ Ions in Li4SiO4–Li2TiO3 Ceramics

Inesh Kenzhina, Artem Leonidovich Kozlovskiy, Yevgen Chikhray, Timur V. Kulsartov, Zhanna A. Zaurbekova, Meiram M. Begentayev, Saulet Askerbekov

2023

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DOI 10.3390/cryst13101526
Data confidence 70 medium
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Abstract

One of the important areas of research in the energy sector is the study of the prospects for using new types of nuclear fuel, including tritium, which is one of the most promising types of fuel for thermonuclear energy. At the same time, for the production of tritium in the required quantities, the one that is the most optimal is the use of blanket materials based on lithium-containing ceramics. This is where tritium is released from lithium under the influence of neutron irradiation. The paper presents the results of an investigation of the influence of two-phase ceramics based on Li4SiO4–Li2TiO3 compounds on the resistance to external influences (mechanical loads) during the accumulation of hydrogen and helium (He2+) in the near-surface layer. The interest in such studies is primarily related to the search for solutions in the field of creating high-strength materials for tritium generation for its further use as nuclear fuel for thermonuclear fusion, as well as to the study of the mechanisms of the influence of different phases on the changes in the strength properties of ceramics, which provides an opportunity to expand fundamental knowledge in this area. The proposed method of obtaining two-phase ceramics by mechanical-chemical mixing and subsequent sintering into spherical particles enables the production of well-structured, high-strength ceramics of specified geometric dimensions (limited only by the dimensions of the mold) with a controlled phase ratio. During the experiments, it was found that increasing the content of Li4SiO4 phase in ceramics leads to an increase in strength characteristics (hardness, resistance to cracking) by 15–20% compared to single-phase ceramics. The most optimal composition of two-phase ceramics with high resistance to destructive embrittlement is the ratio of phases 0.75Li4SiO4–0.25Li2TiO3. One of the factors explaining the increase in resistance to destructive embrittlement under high-dose irradiation for two-phase ceramics is the increased dislocation density and the presence of interphase or intergranular boundaries, the high concentration of which leads to the creation of additional obstacles to the agglomeration of hydrogen and helium in the near-surface layer.