Synthesis of New Symmetrical Diamidophosphates Based on meta-Phenylenediamine under Microwave Irradiation

2023

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DOI 10.1134/s1070363223060099
Data confidence 70 medium
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Abstract

Abstract A new series of diphosphorylated amidophosphates was obtained as a result of the reaction of meta-phenylenediamine with dialkyl phosphites in the presence of CCl4 and triethylamine (Atherton–Todd reaction) under microwave irradiation. Structure of all the obtained amidophosphates was established on the basis of 31P, 1H, 13C NMR, IR spectroscopy and mass spectrometry methods, as well as single crystal X-ray diffraction and elemental analysis data.