Removal of nickel and vanadium from crude oil by using solvent extraction and electrochemical process

PI ", Aliya Kurbanova, Nurlan Akhmetov, Abilmansur Yeshmuratov, Ramiz Zulkharnay, Yerzhigit Sugurbekov, Gulzat Demeuova, Murat Baisariyev, Gulnar K. Sugurbekova

2017

Full text Open access: Gold Metadata (CSL-JSON)
DOI 10.26577/phst-2017-1-127
Data confidence 70 medium
How this score is calculated

It is built from checkable properties of the record itself: whether the article has a DOI, how many independent sources confirmed its data, whether the required fields are filled in, and how recent the latest confirmation is. Disagreement between sources and a missing identifier lower it. A value of 80 or above means the record was published without further checking; 60 to 79 means it is published at reduced confidence, with a manual check advisable. A record verified by an editor by hand is never pushed below 90 by a recalculation. This scores our data about the article, not the article itself.

Abstract

LLP Pavlodar Oil Chemistry Refinery crude oil contain high vanadium and nickel content, which containsmore than 23.09 g/t nickel and 58.59 g/t vanadium. In this study we used two types of metal removing methodssuch as solvent extraction and electrochemical process. The present research is conducted for comparativeanalysis of the deasphalting with organic solvents and electrochemical method. Maximum efficiency ofdeasphalting, with cyclohexane as the solvent, in Soxhlet extractor was 66.4% for nickel and 51.2% forvanadium content from crude oil. Percentage of Ni extraction reached maximum of approximately 20% byusing the electrochemical method in electrolysis cell, which was developed for this research. It consists of threesections: oil and protonating agent (EtOH) solution between two conducting membranes which divides it fromtwo capsules of 10% sulfuric acid and two graphite electrodes which cover all three parts in electrical circuit.Ions of metals’ pass through membranes and remain in acid solutions. The best result was obtained in 60minutes with ethanol to oil ratio of 1 to 3 respectively, current fits in to the range from 0.3A to 0.4A, voltagechanged from 12.8V to 17.3V.