Synthesis and catalytic performance of nickel phosphinite pincer complexes in deoxygenative hydroboration of amides

Aziza Adilkhanova, Valeriya Frolova, Azamat Yessengazin, Ö. Öztopcu, Kristina Gudun, Medet Segizbayev, Nikita A. Matsokin, Anton S. Dmitrienko, Melanie Pilkington, Andrey Y. Khalimon

2023

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DOI 10.1039/d2dt03801c

Data confidence 70 medium

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Abstract

A series of POCN R POCN R2 and POCOP pincer complexes of Ni( ii ) were prepared and their catalytic activities in deoxygenative hydroboration of amides were investigated, resulting in efficient and selective deoxygenation of secondary amides to amines.