Abstract
The object of this research is the process of water disinfection by means of high-frequency electrical discharge. The study addresses the problem of achieving high biological efficiency while reducing energy consumption and avoiding harmful by-products typical of traditional methods such as chlorination or UV irradiation. As a result, a comprehensive theoretical and experimental investigation was conducted, demonstrating that within 20 s of plasma exposure, E. coli, S. aureus, and P. aeruginosa bacteria were inactivated by 99.2–99.9%. The observed efficiency is explained by the synergistic action of reactive oxygen and nitrogen species (•OH, O3, H2O2, NO2−, NO3−) formed in the plasma–water interface. The distinctive features of the obtained results include the establishment of optimal operating parameters-voltage U = 12–18 kV, frequency f ≈ 35 kHz, and gap distance d = 15 mm—under which the normalized specific energy input (SEI) was 6–9 kWh per cubic meter of water. This value represents the standard normalization used for plasma-based treatment systems, where the electrical energy delivered to the reactor is divided by the treated volume (1.0 L in our setup) and scaled to m3 for comparison with other studies, 30–40% lower than in previously reported plasma systems. The validated physicochemical model (Poisson, Navier–Stokes, and continuity equations) matched experimental data with R2 ≥ 0.95, confirming its predictive capability for further scale-up. The practical significance of the results lies in the potential application of this method for decentralized and industrial water treatment systems. The reagent-free, energy-efficient, and environmentally safe nature of the proposed approach makes it suitable for sustainable water purification under real operating conditions.