Spin-crossover semiconductors based on homoleptic tris-diimine Fe( ii ) complexes with fractionally charged TCNQ˙ δ − anions

2025

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DOI 10.1039/d5dt02365c
Data confidence 70 medium
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Abstract

, respectively. The substantially higher conductivity of the bt-containing material was traced to the more uniform charge distribution over the TCNQ units, as established by the crystal structure analysis. Overall, this study provides insight into design principles for solvent-free crystal structures that combine spin crossover with electrical conductivity.