Methods of synthesizing glycoluril-based macrocyclic compounds as precursors for polymeric compounds

Saule K. Kabieva, Gaziza M. Zhumanazarova, Nurdana Kanasheva, А. А. Бакибаев, Svetlana Yu. Panshina, Victor S. Malkov, Elena A. Mamaeva, Alexey S. Knyazev

Journal of Saudi Chemical Society, 2023

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DOI 10.1016/j.jscs.2023.101768

Data confidence 70 medium

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Abstract

This review study considers the classification of data on synthesis methods and practically valuable features of glycoluril-based macrocyclic nitrogen-containing compounds as precursors for polymeric compounds. General data about glycoluril and tetra-N-hydroxymethylglycoluril as parental bases for various macrocyclic compounds were considered. Generalized experimental facts about methods for glycoluril direct N-functionalization and its N-hydroxymethyl derivative reactions in macrocycles and polymeric compound synthesis are given.