On electrochemistry of metal–organic framework Zn 2 (EDTA)(H 2 O)

RSC Advances, 2023

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DOI 10.1039/d3ra00040k
Data confidence 85 high
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Abstract

, were evaluated. It has been established that the studied compound does not give a satisfactory electrochemical response in aqueous electrolytes (both in alkaline and neutral media) due to the strong degradation of the electrode material, which is associated with the high solubility of this MOF representative. Cyclic voltammetric studies showed the presence of two redox processes due to the release of metallic zinc from an electrolyte solution, where two forms of zinc exist in equilibrium (the ZnEDTA complex and the free zinc cation). Therefore, we concluded, it is not possible to use this material as an anode for water-based sodium-ion batteries in contrary to a published research study.