Hydroboration of isocyanates: cobalt-catalyzed vs. catalyst-free approaches

2022

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DOI 10.1039/d2ob01192a
Data confidence 70 medium
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Abstract

Selective hydroboration of isocyanates to formamides was demonstrated using a bench-stable and commercially available cobalt pre-catalyst. The deoxygenation of isocyanates to N -methylamines was performed under catalyst-free and solvent-free conditions.