Abstract
Coal ash-slag waste from coal-fired power plants is a high-volume technogenic material whose resource potential is controlled by particle-size heterogeneity, mineralogical composition, and the occurrence modes of valuable elements. This study investigated Au occurrence in ash-slag waste derived from Ekibastuz coal and evaluated gravity–magnetic preconcentration as a diagnostic first stage for separating Au- and Fe-bearing products. The material was characterized by particle-size analysis, X-ray diffraction, chemical analysis, optical and electron-probe microscopy, atomic absorption analysis (AAS), kinetic spectral analysis (KSA), gravity concentration, and magnetic separation. The feed was an aluminosilicate–ferruginous material dominated by mullite, magnetite, quartz, and hematite. In the coarse material, liberated native Au co-reported with heavy Fe-bearing phases: the vibratory spiral concentrate contained 0.99 g/t Au and 39.00% Fe, corresponding to 52.58% Au recovery and 66.49% Fe recovery. The combined spiral and centrifugal concentrates yielded 1.04 g/t Au at 63.22% recovery, representing an approximately eightfold upgrade relative to the 0.13 g/t feed. In contrast, gravity recovery from the finest fraction was approximately 1%, indicating ultrafine, poorly liberated, or matrix-associated Au. KSA gave higher Au values than AAS, reflecting matrix heterogeneity and method-dependent preparation and detection effects rather than analytical superiority. The results support a size-selective gravity–magnetic preconcentration route followed by targeted mineralogical verification and product-specific downstream extraction.