Hydroethoxycarbonylation of α-olefins at low pressure of carbon(II) oxide in the presence of the PdCl2(PPh3)2–PPh3–AlCl3 system

2017

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DOI 10.1134/s1070363217040089
Data confidence 70 medium
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Abstract

High catalytic activity of the PdCl 2 (PPh 3 ) 2 –PPh 3 –AlCl 3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (≤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6–93.8%.