Induced internal conversion as a probe of enhanced energy transfer in a plasmonic field

Rashid R. Valiev, Niyazbek Kh. Ibrayev, Amina Aymagambetova, Evgeniya V. Seliverstova

2026

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DOI 10.1039/d6cp01284a
Data confidence 85 high
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Abstract

law, especially at short separations, where the latter strongly overestimates the rate. The plasmon-induced enhancement was also described more consistently within the quantum-chemical framework, yielding values close to experiments, whereas the plasmon-modified Förster model tended to overestimate the enhancement at larger distances. The results show that the electric component of the plasmonic near field can significantly enhance nonradiative energy transfer and that this effect is described most adequately within the quantum-chemical supermolecule picture.