Abstract
The paper presents the results of studies of the influence of phase formation processes with variations in annealing temperature on the processes of stabilization of the crystal structure, optical and thermal properties of Nd 2 Zr 2 O 7 ceramics, which have great potential for use in optoelectronic applications due to the transitions of Nd 3 ions, as well as high stability to external factors with the possibility of creating transparent ceramics. During the conducted studies it was established that the stabilization temperature of the Nd 2 Zr 2 O 7 phase is 1100 – 1250 °C, at which the throughput is maximum, and the thermal conductivity coefficient is about 2.1 – 2.2 W/m×K. The assessment of phase transformations and changes in optical properties revealed that an elevation in the annealing temperature, leading to stabilization of the Nd 2 Zr 2 O 7 phase, leads to a decrease in the concentration of oxygen vacancies in the structure of ceramics; however, at temperatures above 1200 °C, the observed growth in oxygen vacancies is due to the effects of substitution of Zr 4+ cations by Nd 3+ cations, which results in formation of additional oxygen vacancies in the structure, alongside impurity inclusions in the form of a cubic phase of Zr(Nd)O 2 , which is a product of phase polymorphic transformations during high-temperature annealing. Alterations in the thermophysical properties of Nd 2 Zr 2 O 7 ceramics are directly dependent on phase formation processes and associated changes in the concentration of oxygen vacancies, which are the determining factor influencing the heat transfer rate. • Stabilization of the Nd 2 Zr 2 O 7 phase, leads to a decrease in the concentration of oxygen vacancies in the structure of ceramics • Results of evaluation of weight contributions of established phases in samples depending on annealing temperature • Results of optical properties of ceramics depending on the annealing temperature • Evaluation results of the thermophysical parameters