Аңдатпа
N-methyl-2-(4-styrylphenyl)-3,4-fulleropyrrolidine synthesis and structureNew stilbene fulleropyrrolidine has been synthesized by С60 fullerene triple-component condensation with sarcosine and trans-4-stilbene carboxaldehyde in Prato reaction conditions.It was demonstrated that primary factor having influence on this reaction final product yield is the homogeneity of the reaction medium.The highest yield of N-methyl-2-(4-styrylphenyl)-3,4-fulleropyrrolidine is observed when reaction performed in xylene and reactive medium is heated.Synthesized compound structure has been studied by IR-, UV-, NMR 1 Н and 13 С spectroscopy as well as by two-dimensional COSY ( 1 H-1 H) and HMQC ( 1 H-13 C) spectra data.The purity and individuality of obtained fulleropyrrolidine have been evaluated using HPLC analysis.N-methyl-2-(4styrylphenyl)-3,4-fulleropyrrolidine synthesis proceeds by the 1,3-dipolar addition to fullerene С60 mechanism through formation of active azomethinilides.N-methyl-2-(4-styrylphenyl)-3,4-fulleropyrrolidine and poly-Nvinylpyrrolidone water-soluble complex has been obtained in dichloromethane.It was shown that complex formation is outcome of fulleropyrrolidine solubilization by PVP chains and lactamic group physical interaction with the fullerene sphere.