Аңдатпа
An IR spectrometric investigation of the dynamic glass transition of ethanol from the rotationally disordered crystal to the orientationally disordered crystal is carried out. The samples considered are thin films formed from the gas phase at a substrate temperature of T=16K. The measurements are performed using the experimental apparatus which has been described in detail in our recent work. The sample thickness was d=2μm, and the typical rate of annealing is approximately 10K∕min. The results are compared with the phase diagram of solid ethanol proposed by M.A. Ramos et al. We observe good agreement between the temperature intervals of existence of the amorphous and crystalline states. The low-temperature amorphous phase (12–70K) is described by the present authors as amorphous solid ethanol by analogy with the amorphous solid water.