Аңдатпа
When two types of fillers are incorporated into a polymer matrix, their interaction can be classified as additive, synergistic, or antagonistic. Although synergistic effects are frequently reported in three-phase polymer nanocomposites, their quantification remains inconsistent due to the absence of a unified and physically meaningful methodology. In this work, existing synergy formulations are critically reviewed, and their limitations in capturing nanoscale effects and filler functionality are identified. Modified equations are then developed by incorporating volume-weighted contributions and explicitly accounting for the functional roles of individual fillers. The proposed framework enables quantitative distinction between cooperative, asymmetric and inhibiting interactions in three-phase systems. The applicability of new formulations is demonstrated through comprehensive analysis of reported polymer nanocomposites systems, covering mechanical, thermal, electrical and functional properties. The results show that cases previously classified as antagonistic using classical equations are consistently identified as synergistic using the modified formulations. This work provides a robust quantitative framework for evaluating synergy in polymer nanocomposites and offers a rational basis for the design of multifunctional hybrid filler systems.